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Electrochemical delithiation of LiMnPO4 in aqueous battery system
Conference paper   Open access

Electrochemical delithiation of LiMnPO4 in aqueous battery system

M. Minakshi, P. Singh, T.B. Issa, S. Thurgate, K. Prince and D. Mitchell
Australian Institute of Nuclear Science and Engineering
14th Australian Conference on Nuclear and Complementary Techniques of Analysis & 8th Vacuum Society of Australia Congress (Wellington, New Zealand, 20/11/2005–22/11/2005)
2005
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Abstract

The electrochemical behavior of lithium manganese phosphate (LIMnPO4) as a cathode material has been investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type L1MnPO4 and the products which arc formed on its oxidation and subsequent reduction were studied. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) and Secondary ion mass spectrometry (SIMS) were used for these investigations. LIMnPO4 is found to be reversibly delithiated on electro oxidation.

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