Journal article
A critical role for Al in regulating the corrosion resistance of nanocrystalline Mo(Si1−xAlx)2 films
Journal of Materials Chemistry, Vol.22(6), pp.2596-2606
2012
Abstract
Novel nanocrystalline Mo(Si1−xAlx)2 films, with differing Al contents were synthesized by double cathode glow discharge. The films exhibited a compact columnar microstructure having a pronounced (111) preferred orientation. The corrosion behaviour of these films were characterized by using various electrochemical techniques including open circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) in 3.5 wt% NaCl solution. The corrosion resistance of the films increased with increasing Al content in the as-synthesized films. The composition and chemical state of the passive layers formed on the films were investigated by X-ray photoelectron spectroscopy (XPS). It was demonstrated that the passive layer formed on the binary MoSi2 film was highly enriched in SiO2 with minor amounts of MoO42−, MoO2 and SiOx. With the increase of Al content in the films, Al2O3 was generated and incorporated into the passive layers, enhancing the corrosion resistance of the films by inhibiting the dissolution of Mo. Built upon the experimental results, the first-principles density-functional theory was applied to calculate the inter-atomic bonding strength in Mo(Si1−xAlx)2 and elucidate the role of Al in controlling the corrosion resistance of the films. The new findings lay a solid basis for the development and application of MoSi2 based corrosion-resistant films.
Details
- Title
- A critical role for Al in regulating the corrosion resistance of nanocrystalline Mo(Si1−xAlx)2 films
- Authors/Creators
- J. Xu (Author/Creator)D. Lai (Author/Creator)Z-H Xie (Author/Creator)P. Munroe (Author/Creator)Z-T Jiang (Author/Creator)
- Publication Details
- Journal of Materials Chemistry, Vol.22(6), pp.2596-2606
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005544965007891
- Copyright
- © The Royal Society of Chemistry 2011
- Murdoch Affiliation
- School of Engineering and Energy
- Language
- English
- Resource Type
- Journal article
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- Collaboration types
- Domestic collaboration
- International collaboration
- Citation topics
- 7 Engineering & Materials Science
- 7.109 Ceramics
- 7.109.1250 MoSi2
- Web Of Science research areas
- Chemistry, Physical
- Materials Science, Multidisciplinary
- ESI research areas
- Materials Science