A metal-mediated diastereoselective synthesis of precursors to the aphid pigment derivatives

R.G.F. Giles; C.A. Joll; M.V. Sargent; D.G. Tilbrook

doi:10.1016/0040-4039(96)01748-0

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A metal-mediated diastereoselective synthesis of precursors to the aphid pigment derivatives

Journal article

Peer reviewed

A metal-mediated diastereoselective synthesis of precursors to the aphid pigment derivatives

R.G.F. Giles, C.A. Joll, M.V. Sargent and D.G. Tilbrook

Tetrahedron Letters, Vol.37(43), pp.7851-7854

1996

DOI: https://doi.org/10.1016/0040-4039(96)01748-0

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Abstract

Chiral compounds 16 and 17, precursors to the aphid insect pigment derivatives, have been prepared in good to high yield, with complete control of the diastereoselectivity at the newly-created chiral centre C-1, through the use of metal phenolates derived from naphthol 3.

Details

Title: A metal-mediated diastereoselective synthesis of precursors to the aphid pigment derivatives
Authors/Creators: R.G.F. Giles (Author/Creator) - Murdoch University
C.A. Joll (Author/Creator) - Murdoch University
M.V. Sargent (Author/Creator) - German Federal Chancellery
D.G. Tilbrook (Author/Creator)
Publication Details: Tetrahedron Letters, Vol.37(43), pp.7851-7854
Publisher: Elsevier BV
Identifiers: 991005541595307891
Murdoch Affiliation: School of Chemical and Mathematical Science
Language: English
Resource Type: Journal article

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Collaboration types: Domestic collaboration
Citation topics: 1 Clinical & Life Sciences; 1.219 Cancer Drugs; 1.219.1527 Naphthoquinone Derivatives
Web Of Science research areas: Chemistry, Organic
ESI research areas: Chemistry