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Assessing the Potential for Ion Selective Electrodes and Dual Wavelength UV Spectroscopy as a Rapid on-Farm Measurement of Soil Nitrate Concentration
Journal article   Open access   Peer reviewed

Assessing the Potential for Ion Selective Electrodes and Dual Wavelength UV Spectroscopy as a Rapid on-Farm Measurement of Soil Nitrate Concentration

Rory Shaw, A. Prysor Williams, Anthony Miller and Davey L. Jones
Agriculture (Basel), Vol.3(3), pp.327-341
2013
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Open Access

Abstract

Agriculture Agronomy Life Sciences & Biomedicine Science & Technology
Current fertiliser recommendations for nitrogen are limited in their accuracy and may be improved by the use of simple on-farm soil rapid tests. This paper investigates the potential for using nitrate (NO3-) ion selective electrodes (ISEs) and dual wavelength UV spectroscopy as part of a rapid soil NO3- diagnostic test. Three soil types, representing the major soil types for agriculture in the western UK, were tested. For the three soils, the ISE rapid test procedure gave a near 1:1 response (r(2) = 0.978, 0.968, 0.989) compared to the internationally-approved standard laboratory method. However, the accuracy of the ISE rapid test was reduced at low soil NO3- concentrations (<10 mg NO3- L-1). We also show that NO3- analysis of H2O soil extracts by dual wavelength UV spectroscopy was also highly correlated (r(2) = 0.978, 0.983, 0.991) to the standard laboratory method. We conclude that both ISE and dual wavelength UV spectroscopy have clear potential to be used for the rapid on-farm determination of soil NO3- concentration. Barriers to use of these field-based assessment tools include, farmer perception of cost-benefit, general attitude to new technologies and the ability to generate useful fertiliser use strategies from soil NO3- measurements.

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UN Sustainable Development Goals (SDGs)

This output has contributed to the advancement of the following goals:

#2 Zero Hunger
#13 Climate Action
#14 Life Below Water

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