Journal article
Catalytic hydrodehalogenation of halon 1211 (CBrClF2) over carbon-supported palladium catalysts
Applied Catalysis B: Environmental, Vol.44(3), pp.253-261
2003
Abstract
The hydrodehalogenation of halon 1211 over Pd/C catalysts was studied over a relatively narrow temperature range, from 453 to 573 K. The main products of the reaction are CH2F2 and CHBrF2 with CHClF2 formed as a minor product. Pd/C catalysts show high initial activities but undergo gradual deactivation before reaching a steady-state activity level. Experimental results suggest that CHBrF2 and CHClF2 are formed via the secondary reaction of CF2 with HBr and HCl.
Details
- Title
- Catalytic hydrodehalogenation of halon 1211 (CBrClF2) over carbon-supported palladium catalysts
- Authors/Creators
- H. Yu (Author/Creator)E.M. Kennedy (Author/Creator)M. Azhar Uddin (Author/Creator)B.Z. Dlugogorski (Author/Creator)
- Publication Details
- Applied Catalysis B: Environmental, Vol.44(3), pp.253-261
- Publisher
- Elsevier
- Identifiers
- 991005541401407891
- Copyright
- © 2003 Elsevier B.V.
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.90 Water Treatment
- 2.90.1763 Zero-Valent Iron
- Web Of Science research areas
- Chemistry, Physical
- Engineering, Chemical
- Engineering, Environmental
- ESI research areas
- Chemistry