Journal article
Electrochemical behavior of anatase TiO2 in aqueous lithium hydroxide electrolyte
Journal of Applied Electrochemistry, Vol.36(5), pp.599-602
2006
Abstract
The electrochemical behavior of titanium dioxide (TiO2) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO2 shows that Li x TiO2, Ti2O3, Ti2O and TiO are formed. The formation of Li x TiO2 is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO2. The formation of Li x TiO2 is electro reversible. In this respect, the electrochemical behavior of TiO2 in concentrated aqueous lithium hydroxide electrolyte is similar to that for lithium perchlorate (LiClO4) non-aqueous media.
Details
- Title
- Electrochemical behavior of anatase TiO2 in aqueous lithium hydroxide electrolyte
- Authors/Creators
- M. Minakshi (Author/Creator)P. Singh (Author/Creator) - Murdoch UniversityT.B. Issa (Author/Creator) - Murdoch UniversityS. Thurgate (Author/Creator) - Murdoch University
- Publication Details
- Journal of Applied Electrochemistry, Vol.36(5), pp.599-602
- Publisher
- Kluwer Academic Publishers
- Identifiers
- 991005542742107891
- Copyright
- Springer 2006
- Murdoch Affiliation
- School of Chemical and Mathematical Science
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.62 Electrochemistry
- 2.62.52 Electrode Materials
- Web Of Science research areas
- Electrochemistry
- ESI research areas
- Chemistry