Electrochemical studies on neutral triple-bridged di-ruthenium compounds.

T. Arthur; R. Contreras; G.A. Heath; G. Hefter; A.J. Lindsay; D.J.A. Riach; T.A. Stephenson

doi:10.1016/S0022-328X(00)91864-3

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Electrochemical studies on neutral triple-bridged di-ruthenium compounds.

Journal article

Peer reviewed

Electrochemical studies on neutral triple-bridged di-ruthenium compounds.

T. Arthur, R. Contreras, G.A. Heath, G. Hefter, A.J. Lindsay, D.J.A. Riach and T.A. Stephenson

Journal of Organometallic Chemistry, Vol.179(4), pp.C49-C54

1979

DOI: https://doi.org/10.1016/S0022-328X(00)91864-3

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Abstract

Voltammetric studies reveal that, like [Ru2Cl4(PPh3)4(CO)], triply-bridged complexes [Ru2Cl4L5] (L = PClPh2, PMePh2, PEt2Ph) are reversibly oxidized to [Ru2Cl4L5]+. The mixed valence complexes [Ru2Cl5L3Y] (L = PPh3, P(tol)3; Y = CO, CS) undergo a corresponding reduction to [Ru2Cl5L3Y]−; whereas [Ru2Cl5L4] (L = PEt2Ph, As(tol)3) and [Ru2Cl6(AsPh3)3] are both reduced oxidised in reversible one-electron steps. For the bridging (RuCl3Ru)z+ moiety, the redox series z = 1, 2, 3, 4 is established.

Details

Title: Electrochemical studies on neutral triple-bridged di-ruthenium compounds.
Authors/Creators: T. Arthur (Author/Creator)
R. Contreras (Author/Creator)
G.A. Heath (Author/Creator)
G. Hefter (Author/Creator)
A.J. Lindsay (Author/Creator)
D.J.A. Riach (Author/Creator)
T.A. Stephenson (Author/Creator)
Publication Details: Journal of Organometallic Chemistry, Vol.179(4), pp.C49-C54
Publisher: Elsevier BV
Identifiers: 991005541951207891
Murdoch Affiliation: Murdoch University
Language: English
Resource Type: Journal article

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