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Electron-helium S-wave model benchmark calculations. I. Single ionization and single excitation
Journal article   Open access   Peer reviewed

Electron-helium S-wave model benchmark calculations. I. Single ionization and single excitation

P.L. Bartlett and A.T. Stelbovics
Physical Review A - Atomic, Molecular, and Optical Physics, Vol.81(2), Article number 022715
2010
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Abstract

A full four-body implementation of the propagating exterior complex scaling (PECS) method is developed and applied to the electron-impact of helium in an S-wave model. Time-independent solutions to the Schrödinger equation are found numerically in coordinate space over a wide range of energies and used to evaluate total and differential cross sections for a complete set of three- and four-body processes with benchmark precision. With this model we demonstrate the suitability of the PECS method for the complete solution of the full electron-helium system. Here we detail the theoretical and computational development of the four-body PECS method and present results for three-body channels: single excitation and single ionization. Four-body cross sections are presented in the sequel to this article. The calculations reveal structure in the total and energy-differential single-ionization cross sections for excited-state targets that is due to interference from autoionization channels and is evident over a wide range of incident electron energies.

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Domestic collaboration
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2 Chemistry
2.15 Physical Chemistry
2.15.664 Dissociative Electron Attachment
Web Of Science research areas
Optics
Physics, Atomic, Molecular & Chemical
ESI research areas
Physics
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