Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII)

D.R. Rosseinsky; M.J. Nicol

doi:10.1039/J19700001196

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Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII)

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Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII)

D.R. Rosseinsky and M.J. Nicol

Journal of the Chemical Society A: Inorganic, Physical, Theoretical, pp.1196-1200

1970

DOI: https://doi.org/10.1039/J19700001196

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Abstract

The rate law k[CrVI][VIV]2[H+]n/VV], with n < 1, is confirmed, and differences from the iron(II)–chromium(IV) result are explained. With proper interpretation the comparability of iron(II) with vanadium(IV) reactions is preserved. The reaction of vanadium(IV) with manganese(VIII) appears to be initially just of the second order, but non-stoicheiometry and acceleration by product manganese(II) introduce later complications only qualitatively resolvable.

Details

Title: Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII)
Authors/Creators: D.R. Rosseinsky (Author/Creator)
M.J. Nicol (Author/Creator)
Publication Details: Journal of the Chemical Society A: Inorganic, Physical, Theoretical, pp.1196-1200
Publisher: Royal Society of Chemistry
Identifiers: 991005540200807891
Copyright: 1970 RSC
Murdoch Affiliation: Murdoch University
Language: English
Resource Type: Journal article

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