Journal article
Electrospun PVDF–TiO2 with tuneable TiO2 crystal phases: synthesis and application in photocatalytic redox reactions
Journal of Materials Chemistry A, Vol.5(2), pp.641-648
2017
Abstract
Electrospinning and hydrothermal treatment were employed to fabricate polyvinylidene fluoride (PVDF)–titanium dioxide composite photocatalytic membranes with different anatase, brookite and rutile compositions. The crystal phases were manipulated by adjusting the urea : hydrochloric acid ratio and the concentration of tetrabutyl titanate in the hydrothermal solution, forming either bicrystalline or tricrystalline TiO2. The sample with the highest photoproduction of methane from CO2 (19.8 μmol per gcatalyst per h) showed a low activity in the photooxidation of phenol in aqueous solution under UV irradiation. Based on the results obtained, the crystal phase composition and microstructure of the PVDF–TiO2 greatly influenced the photocatalytic reduction of CO2. Electron spin resonance and XRD indicated a difference in Ti3+ content and this is believed to affect the rate of photodegradation of phenol. This study revealed that small, controlled changes in TiO2 phase and morphology on the electrospun PVDF produced photocatalytic membranes with distinctly different activities.
Details
- Title
- Electrospun PVDF–TiO2 with tuneable TiO2 crystal phases: synthesis and application in photocatalytic redox reactions
- Authors/Creators
- J.Z.Y. Tan (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationN.M. Nursam (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationF. Xia (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationY.B. Truong (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationI.L. Kyratzis (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationX. Wang (Author/Creator) - Commonwealth Scientific and Industrial Research OrganisationR.A. Caruso (Author/Creator) - Commonwealth Scientific and Industrial Research Organisation
- Publication Details
- Journal of Materials Chemistry A, Vol.5(2), pp.641-648
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005543676307891
- Copyright
- © 2016 Royal Society of Chemistry
- Murdoch Affiliation
- School of Engineering and Information Technology
- Language
- English
- Resource Type
- Journal article
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InCites Highlights
These are selected metrics from InCites Benchmarking & Analytics tool, related to this output
- Collaboration types
- Domestic collaboration
- International collaboration
- Citation topics
- 2 Chemistry
- 2.74 Photocatalysts
- 2.74.5 TiO2 Photocatalysis
- Web Of Science research areas
- Chemistry, Physical
- Energy & Fuels
- Materials Science, Multidisciplinary
- ESI research areas
- Materials Science