Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

G. Hefter; Y. Marcus; W.E. Waghorne

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Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

Journal article

Peer reviewed

Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

G. Hefter, Y. Marcus and W.E. Waghorne

Chemical Reviews, Vol.102(8), pp.2773-2836

2002

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Abstract

A wide-ranging critically evaluated compilation of the standard molar enthalpies and entropies of transfer of electrolytes from water to mixed aqueous-organic solvents were shown. For this compilation, the reported values were recalculated to obtain a consistent format that enabled comparisons to be made among the data. These whole-salt data were then split into the transfer functions of the individual ions, using an appropriate extrathermodynamic assumption.

Details

Title: Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents
Authors/Creators: G. Hefter (Author/Creator)
Y. Marcus (Author/Creator)
W.E. Waghorne (Author/Creator)
Publication Details: Chemical Reviews, Vol.102(8), pp.2773-2836
Publisher: American Chemical Society
Identifiers: 991005545061307891
Murdoch Affiliation: School of Chemical and Mathematical Science
Language: English
Resource Type: Journal article

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