Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10

H. Yu; E.M. Kennedy; W-H Ong; J.C. Mackie; W. Han; B.Z. Dlugogorski

doi:10.1021/ie071400z

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Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10

Journal article

Peer reviewed

Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10

H. Yu, E.M. Kennedy, W-H Ong, J.C. Mackie, W. Han and B.Z. Dlugogorski

Industrial & Engineering Chemistry Research, Vol.47(8), pp.2579-2584

2008

DOI: https://doi.org/10.1021/ie071400z

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Abstract

The gas-phase pyrolysis of n-C4F10 has been studied experimentally in a plug flow, isothermal α-alumina reactor at atmospheric pressure and various residence times over the temperature range of 873 to 1148 K. The major products are C2F6, C2F 4, C3F8, and C3F6 (CF3-CF=CF2). Minor products include Cyclo-C 4F8 (c-C4F8) and CO2. CF4 is detected in trace amounts at high temperatures. A kinetic reaction scheme involving 20 species and 30 reactions is developed and used to model n-C4F10 pyrolysis. A generally satisfactory agreement between experimental and modeling results is obtained on the conversion levels of n-C4F10 and the rates of formation of C2F6 and C3F8.

Details

Title: Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10
Authors/Creators: H. Yu (Author/Creator) - University of Newcastle Australia
E.M. Kennedy (Author/Creator) - University of Newcastle Australia
W-H Ong (Author/Creator) - University of Newcastle Australia
J.C. Mackie (Author/Creator) - University of Newcastle Australia
W. Han (Author/Creator) - University of Newcastle Australia
B.Z. Dlugogorski (Author/Creator) - University of Newcastle Australia
Publication Details: Industrial & Engineering Chemistry Research, Vol.47(8), pp.2579-2584
Publisher: American Chemical Society
Identifiers: 991005545316807891
Copyright: © 2008 American Chemical Society.
Murdoch Affiliation: Murdoch University
Language: English
Resource Type: Journal article

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Citation topics: 2 Chemistry; 2.1 Synthesis; 2.1.883 Fluorination Chemistry
Web Of Science research areas: Engineering, Chemical
ESI research areas: Chemistry