Fluoride complexes of the alkali metal ions

C.B. Chan; N.H. Tioh; G.T. Hefter

doi:10.1016/S0277-5387(00)84633-1

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Fluoride complexes of the alkali metal ions

Journal article

Peer reviewed

Fluoride complexes of the alkali metal ions

C.B. Chan, N.H. Tioh and G.T. Hefter

Polyhedron, Vol.3(7), pp.845-851

1984

DOI: https://doi.org/10.1016/S0277-5387(00)84633-1

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Abstract

Measurements by fluoride ion-selective electrode potentiometry on the very weak monofluoride complexes of the alkali metal ions in aqueous solution at 25°C and an ionic strength of 1M indicate their stability constants lie in the order Li+ > Na+ > K+ > Rb+ ⋍ Cs+. Data at varying ionic strengths and temperatures were used to calculate infinite dilution stability constants and enthalpies and entropies of complexation for LiF and NaF.

Details

Title: Fluoride complexes of the alkali metal ions
Authors/Creators: C.B. Chan (Author/Creator) - University of Malaya
N.H. Tioh (Author/Creator) - University of Malaya
G.T. Hefter (Author/Creator) - Murdoch University
Publication Details: Polyhedron, Vol.3(7), pp.845-851
Publisher: Elsevier
Identifiers: 991005543506707891
Murdoch Affiliation: School of Mathematical and Physical Sciences
Language: English
Resource Type: Journal article

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Collaboration types: Domestic collaboration; International collaboration
Citation topics: 2 Chemistry; 2.89 Ionic, Molecular & Complex Liquids; 2.89.462 Excess Molar Volumes
Web Of Science research areas: Chemistry, Inorganic & Nuclear; Crystallography
ESI research areas: Chemistry