Journal article
Gas-phase reaction of CCl2F2 (CFC-12) with methane
Chemosphere, Vol.53(9), pp.1189-1191
2003
Abstract
Gas-phase reaction of CFC-12 (CCl2F2) with methane was carried out in a plug flow reactor over the temperature range of 873-1123 K. The major organic halocarbons formed during the reaction were C 2F4, C2H2F2, CHClF 2, CH3Cl, C3H2F6 and CCl3F. The formation of all products except C2H 2F2 decreased with temperature, while the selectivity to C2H2F2 (difluoroethylene) increased with temperature and reached ≈80% at 1123 K. Under these reaction conditions, methane acts as hydrogen and carbon source, resulting in the formation of an unsaturated C2 hydrofluorocarbon from two C1 precursors.
Details
- Title
- Gas-phase reaction of CCl2F2 (CFC-12) with methane
- Authors/Creators
- Md.A. Uddin (Author/Creator)E.M. Kennedy (Author/Creator)B.Z. Dlugogorski (Author/Creator)
- Publication Details
- Chemosphere, Vol.53(9), pp.1189-1191
- Publisher
- Elsevier
- Identifiers
- 991005545566207891
- Copyright
- © 2003 Elsevier Ltd.
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.90 Water Treatment
- 2.90.1763 Zero-Valent Iron
- Web Of Science research areas
- Environmental Sciences
- ESI research areas
- Environment/Ecology