Journal article
Goodbye to S2− in aqueous solution
Chemical Communications, Vol.54(16), pp.1980-1983
2018
Abstract
New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2−(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2−(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.
Details
- Title
- Goodbye to S2− in aqueous solution
- Authors/Creators
- P.M. May (Author/Creator) - Murdoch UniversityD. Bátka (Author/Creator) - Murdoch UniversityG. Hefter (Author/Creator) - Murdoch UniversityE. Königsberger (Author/Creator) - Murdoch UniversityD. Rowland (Author/Creator) - Murdoch University
- Publication Details
- Chemical Communications, Vol.54(16), pp.1980-1983
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005543646007891
- Copyright
- © 2018 Royal Society of Chemistry
- Murdoch Affiliation
- School of Engineering and Information Technology
- Language
- English
- Resource Type
- Journal article
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- Collaboration types
- Domestic collaboration
- Citation topics
- 8 Earth Sciences
- 8.8 Geochemistry, Geophysics & Geology
- 8.8.752 Isotope Geochemistry
- Web Of Science research areas
- Chemistry, Multidisciplinary
- ESI research areas
- Chemistry