Journal article
Homoanomeric effect in the 1,2-dimethoxyethyl radical
Australian Journal of Chemistry, Vol.56(5), pp.429-436
2003
Abstract
A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with the β-C-O bond. The magnitude of this stabilization is predicted to be ∼ 10-12 kJ mol-1 at the G3(MP2)-RAD and DBS-RAD levels of theory.
Details
- Title
- Homoanomeric effect in the 1,2-dimethoxyethyl radical
- Authors/Creators
- D.J. Henry (Author/Creator)A.L.J. Beckwith (Author/Creator)L. Radom (Author/Creator)
- Publication Details
- Australian Journal of Chemistry, Vol.56(5), pp.429-436
- Publisher
- Commonwealth Scientific and Industrial Research Organization Publishing
- Identifiers
- 991005543172607891
- Copyright
- © CSIRO 2003
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.1 Synthesis
- 2.1.1299 Radical Cyclization
- Web Of Science research areas
- Chemistry, Multidisciplinary
- ESI research areas
- Chemistry