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In-depth fine structure of carbon micropores with positron annihilation lifetime spectroscopy
Journal article   Open access

In-depth fine structure of carbon micropores with positron annihilation lifetime spectroscopy

Kei Kubo, Hayato Otsuka, Daisuke Saeki, Ayumi Furuse, Takuya Hayashi, Piotr Kowalczyk, Toshio Sakai and Katsumi Kaneko
Chemical Physics Letters, Vol.890, 142741
2026
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CC BY V4.0 Open Access

Abstract

Ultramicroporosimetry PALS Positronium Activated carbon fibre Ar adsorption
The detailed pore structure analysis of nanoporous carbons is essential for designing high-performance materials for clean-energy technologies. We used activated carbon fibres (ACFs) with average pore sizes of 0.8 and 1.3 nm. Using an ACF-polytetrafluoroethylene sample, the carbon-specific positron annihilation lifetime (CS-PAL) of the ACF was determined based on the lifetime versus ACF content relationship. Pore sizes determined by CS-PAL spectroscopy were smaller than those reported by Ar adsorption: ACFs of 0.8 and 1.3 nm were 0.4 and 0.2 nm, respectively, suggesting that the 0.8 nm-ACF exhibited single-layered graphitic islands within the pore and the 1.3 nm-ACF had plain pore walls.

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