Logo image
Intermolecular Casimir-Polder forces in water and near surfaces
Journal article   Open access   Peer reviewed

Intermolecular Casimir-Polder forces in water and near surfaces

P. Thiyam, C. Persson, B.E. Sernelius, D.F. Parsons, A. Malthe-Sørenssen and M. Boström
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, Vol.90(3), Article 032122
2014
pdf
Intermolecular_Casimir-Polder_forces.pdfDownloadView
Published (Version of Record) Open Access
url
Link to Published Version *Subscription may be requiredView

Abstract

The Casimir-Polder force is an important long-range interaction involved in adsorption and desorption of molecules in fluids. We explore Casimir-Polder interactions between methane molecules in water, and between a molecule in water near SiO2 and hexane surfaces. Inclusion of the finite molecular size in the expression for the Casimir-Polder energy leads to estimates of the dispersion contribution to the binding energies between molecules and between one molecule and a planar surface.

Details

Metrics

140 File views/ downloads
43 Record Views
Logo image