Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution

D.R. Rosseinsky; M.J. Nicol

doi:10.1039/TF9656102718

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Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution

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Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution

D.R. Rosseinsky and M.J. Nicol

Transactions of the Faraday Society, Vol.61, pp.2718-2723

1965

DOI: https://doi.org/10.1039/TF9656102718

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Abstract

The reaction 4MnIIfMnVxI = 5MnIII obeyed the rate equation, rate = k[Mnu]2[MnvII]. In lithium perchlorate media the [H+]-dependence was found to be k = k~H+]+ko. Activation energies and entropies were compared with standard values for formation of intermediate species in an examination of possible mechanisms.

Details

Title: Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution
Authors/Creators: D.R. Rosseinsky (Author/Creator)
M.J. Nicol (Author/Creator)
Publication Details: Transactions of the Faraday Society, Vol.61, pp.2718-2723
Publisher: Royal Society of Chemistry
Identifiers: 991005544024607891
Murdoch Affiliation: Murdoch University
Language: English
Resource Type: Journal article

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