Journal article
Kinetics of the bromate–iodide and iodate–iodide reactions by pH-stat techniques
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol.72(0), pp.568-574
1976
Abstract
Buffer-free pH-stat methods were applied to kinetic investigations of the iodate-iodide and bromate-iodide reactions in the pH range 3-4 yielding the rate laws v′ = k′0[H+]2[I -]2[IO3-] and v = k0 [H+]2[I-][BrO3-] + k 1[H+][I-][BrO3-]. In addition, for [I-] and [IO3-] of the order of 10-2M (M = mol dm-3) the rate of reaction was 4th order in [I-], 2nd order in [IO3-], and the order with respect to [H+] increased from 1st towards 3rd as [H+] decreased from 8 × 10-7 M to 4 × 10-8 M
Details
- Title
- Kinetics of the bromate–iodide and iodate–iodide reactions by pH-stat techniques
- Authors/Creators
- A.F.M. Barton (Author/Creator)H.N. Cheong (Author/Creator)R.E. Smidt (Author/Creator)
- Publication Details
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol.72(0), pp.568-574
- Publisher
- Faraday Division of the Chemical Society
- Identifiers
- 991005544032407891
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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