Journal article
LiAsF6 in propylene carbonate—acetonitrile for primary lithium batteries
Journal of Power Sources, Vol.10(1), pp.13-21
1983
Abstract
1M LiAsF6 in 50% v/v propylene carbonate—acetonitrile (PC-AN) is an electrolyte solution which offers improved cathode utilization, improved energy efficiency and more stable discharge voltages when used in primary lithium batteries with MnO2, TiS2, Cu2S, CuS, MoO3, V2O5, V6O13 and NbSe3 cathodes. Incorporation of solvated Li+ into the cathodic material may be part of the cathodic process, and the lower viscosity and lower molar volume of acetonitrile, which is a solvator of Li+ in PC/AN mixtures, are thought to be responsible for the major improvement over LiAsF6 in PC as electrolyte solution for these cells.
Details
- Title
- LiAsF6 in propylene carbonate—acetonitrile for primary lithium batteries
- Authors/Creators
- K. Cedzynska (Author/Creator) - Murdoch UniversityA.J. Parker (Author/Creator) - Murdoch UniversityP. Singh (Author/Creator) - Murdoch University
- Publication Details
- Journal of Power Sources, Vol.10(1), pp.13-21
- Publisher
- Elsevier BV
- Identifiers
- 991005540266207891
- Copyright
- © 2014 Elsevier B.V.
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Physical
- Electrochemistry
- Energy & Fuels
- Materials Science, Multidisciplinary
- ESI research areas
- Materials Science