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Microwave-Induced molecular rearrangements. Flash Thermolysis in the Gas-Phase and in solution: Synthesis of Quinolones and Naphthyridones
Journal article   Peer reviewed

Microwave-Induced molecular rearrangements. Flash Thermolysis in the Gas-Phase and in solution: Synthesis of Quinolones and Naphthyridones

D. Lecoq, B.A. Chalmers, R.N. Veedu, D. Kvaskoff, P.V. Bernhardt and C. Wentrup
Australian Journal of Chemistry, Vol.62(12)
2009
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Abstract

3- and 4-Pyridyliminopropadienones were prepared by flash vacuum thermolysis of Meldrum’s acid derivatives and characterized by low temperature IR spectroscopy. They react with dimethylamine to afford 1,5-, 1,6-, and 1,7-naphthyridones. The same naphthyridones are also obtained by microwave irradiation of the Meldrum’s acid derivatives. Quinolones were obtained by microwave irradiation of phenylaminomethylene-Meldrum’s acids and 1-phenylpyrrole-2,3-diones.

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Citation topics
2 Chemistry
2.1 Synthesis
2.1.834 Cycloaddition Reactions
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry
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