Journal article
Nucleophilic substitution reactions of thienyl neopentyl substrates
Australian Journal of Chemistry, Vol.40(1), pp.49-60
1987
Abstract
The reaction of the chlorides (4)-(6), which are both neopentylic and thenylic , were studied. The chloride (4), unlike its analogue (13) in the benzene series, undergoes ready solvolysis with alcohols to give the corresponding ethers, e.g. (7)-(9). The chlorides (5) and (6) react more slowly than (4) but undergo methanolysis to give the methyl ethers (11) and (12) respectively. In the dipolar aprotic solvents, dimethyl sulfoxide and dimethylformamide, the reactions of the chlorides (4), (5) and (6) with the thiolate salt (16) appear to proceed by an SN1-like, an SN(AEAE) and an SRNl process respectively.
Details
- Title
- Nucleophilic substitution reactions of thienyl neopentyl substrates
- Authors/Creators
- F.I. McLure (Author/Creator)R.K. Norris (Author/Creator)K. Wilson (Author/Creator)
- Publication Details
- Australian Journal of Chemistry, Vol.40(1), pp.49-60
- Publisher
- Commonwealth Scientific and Industrial Research Organization Publishing
- Identifiers
- 991005545220207891
- Copyright
- © 1987 CSIRO
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.1 Synthesis
- 2.1.824 Solvolysis
- Web Of Science research areas
- Chemistry, Multidisciplinary
- ESI research areas
- Chemistry