Journal article
Partial Molar Volumes of Cyclic Alcohols at Infinite Dilution in Water at TemperaturesT= (298 to 373) K and Pressure of 0.5 MPa†
Journal of Chemical & Engineering Data, Vol.54(2), pp.459-463
2009
Abstract
Density data for dilute aqueous solutions of six cyclic alcohols (cyclopentanol, cyclohexanol, cycloheptanol, cyclooctanol, cyclohexylmethanol, and 2-cyclohexylethanol) obtained using a flow vibrating-tube densimeter are presented together with partial molar volumes at infinite dilution (standard partial molar volumes) calculated from the measured data. The measurements were performed at temperatures from T = 298 K up to T = 373 K at pressures close to the atmospheric pressure [(0.4 to 0.5) MPa]. Trends in homologous series are discussed, and group contributions to standard partial molar volume are evaluated. Using the group contributions, standard partial molar volumes of three additional solutes were estimated and compared with data from the literature.
Details
- Title
- Partial Molar Volumes of Cyclic Alcohols at Infinite Dilution in Water at TemperaturesT= (298 to 373) K and Pressure of 0.5 MPa†
- Authors/Creators
- I. Cibulka (Author/Creator) - University of Chemistry and Technology, PragueL. Hnědkovský (Author/Creator) - University of Chemistry and Technology, Prague
- Publication Details
- Journal of Chemical & Engineering Data, Vol.54(2), pp.459-463
- Publisher
- American Chemical Society
- Identifiers
- 991005542175307891
- Copyright
- © 2008 American Chemical Society
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Multidisciplinary
- Engineering, Chemical
- Thermodynamics
- ESI research areas
- Chemistry