Journal article
Partial molar volumes of selected aliphatic alcohols at infinite dilution in water at temperatures T= (278 to 573) K and pressures up to 30 MPa
Journal of Chemical & Engineering Data, Vol.56(12), pp.4564-4576
2011
Abstract
Density data for dilute aqueous solutions of four aliphatic alcohols (2,2-dimethylpropane-1-ol, 2-methylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)butane-1-ol) and one ether alcohol (3,3,7,7-tetrakis(hydroxymethyl)-5-oxanonane) were obtained using both the Anton Paar DSA 5000 vibrating-tube densimeter and the laboratory-made flow densimeter. They are presented together with partial molar volumes at infinite dilution (standard molar volumes) calculated from the measured data. The measurements were performed at temperatures T = (278 to 573) K and at pressures up to p = 30 MPa. Trends in homologous series are discussed, and the group additivity scheme proposed recently is applied to the solutes investigated.
Details
- Title
- Partial molar volumes of selected aliphatic alcohols at infinite dilution in water at temperatures T= (278 to 573) K and pressures up to 30 MPa
- Authors/Creators
- L. Šimurka (Author/Creator)I. Cibulka (Author/Creator)L. Hnědkovský (Author/Creator)
- Publication Details
- Journal of Chemical & Engineering Data, Vol.56(12), pp.4564-4576
- Publisher
- American Chemical Society
- Identifiers
- 991005541725807891
- Copyright
- © 2011 American Chemical Society
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Multidisciplinary
- Engineering, Chemical
- Thermodynamics
- ESI research areas
- Chemistry