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Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
Journal article   Open access   Peer reviewed

Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5

N.A. Khan, E.M. Kennedy, B.Z. Dlugogorski, A.A. Adesina and M. Stockenhuber
Catalysis Communications, Vol.53, pp.42-46
2014
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Abstract

Synthesis gas (CO + H2) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis gas from CH4, under partial oxidation conditions using N2O as oxidant. With O2 as oxidant over the same Co-ZSM-5 catalyst, cobalt on alumina and Fe-ZSM-5, only COx and H2O are formed. Isolated Co2 + sites in the ZSM-5 support are proposed as the active sites for H2 (synthesis gas) formation.

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2 Chemistry
2.41 Catalysts
2.41.366 Selective Catalytic Reduction
Web Of Science research areas
Chemistry, Physical
ESI research areas
Chemistry
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