Journal article
Polarographic studies of copper(II) in aqueous dimethylsulphoxide and aqueous acetone and free energy of transfer of copper(I) and copper(II) from water to dimethyl-sulphoxide-water mixtures
Electrochimica Acta, Vol.33(12), pp.1785-1787
1988
Abstract
Polarographic studies of Cu(ClO4)2 in aqueous dimethylsulphoxide (DMSO) mixtures have identified compositions in which Cu(I) is stable. The half-wave potentials EView the MathML source, of Cu(II)/Cu(I) and Cu(I)/Cu(Hg) decrease in DMSO-water mixtures and values of free energies of transfer, ΔGtr, of Cu(II) and Cu(I) from water to aqueous DMSO are reported. Similar measurement in aqueous acetone mixtures show that ΔGtr Cu(II) increases upon addition of acetone.
Details
- Title
- Polarographic studies of copper(II) in aqueous dimethylsulphoxide and aqueous acetone and free energy of transfer of copper(I) and copper(II) from water to dimethyl-sulphoxide-water mixtures
- Authors/Creators
- D.M. Muir (Author/Creator) - Murdoch UniversityC. Kenna (Author/Creator) - Murdoch UniversityP. Singh (Author/Creator) - Murdoch University
- Publication Details
- Electrochimica Acta, Vol.33(12), pp.1785-1787
- Publisher
- Elsevier
- Identifiers
- 991005541039307891
- Copyright
- © 1988 Published by Elsevier Ltd.
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Electrochemistry
- ESI research areas
- Chemistry