Reaction of Iminopropadienones with Amines-Formation of Zwitterionic Intermediates, Ketenes, and Ketenimines

R.N. Veedu; O.J. Kokas; I. Couturier-Tamburelli; R. Koch; J-P Aycard; F. Borget; C. Wentrup

doi:10.1021/jp803351q

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Reaction of Iminopropadienones with Amines-Formation of Zwitterionic Intermediates, Ketenes, and Ketenimines

Journal article

Peer reviewed

Reaction of Iminopropadienones with Amines-Formation of Zwitterionic Intermediates, Ketenes, and Ketenimines

R.N. Veedu, O.J. Kokas, I. Couturier-Tamburelli, R. Koch, J-P Aycard, F. Borget and C. Wentrup

The Journal of Physical Chemistry A, Vol.112(40), pp.9742-9750

2008

DOI: https://doi.org/10.1021/jp803351q

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Abstract

Five aryliminopropadienones 4a−d have been synthesized by flash vacuum thermolysis (FVT) by using two different precursors in each case. These compounds were deposited at 50 K at a pressure of ca. 10−6 mbar together with three different nucleophiles, namely, trimethylamine (TMA), dimethylamine (DMA), and diethylamine (DEA), in order to study their reactions as neat solids during warm-up by FTIR spectroscopy. The reaction with TMA showed that a zwitterionic species (5 and/or 6) was formed in all the cases. With DMA and DEA, an α-oxoketenimine and/or an imidoylketene (7 and 8 or 9 and 10) was formed as the final product. In addition, several bands were observed, which can be assigned to zwitterionic intermediates (11 or 12). Optimized structures and vibrational spectra for all products were calculated at the B3LYP/6-31G(d) level of theory by using the polarizable continuum model (ε = 5).

Details

Title: Reaction of Iminopropadienones with Amines-Formation of Zwitterionic Intermediates, Ketenes, and Ketenimines
Authors/Creators: R.N. Veedu (Author/Creator)
O.J. Kokas (Author/Creator)
I. Couturier-Tamburelli (Author/Creator)
R. Koch (Author/Creator)
J-P Aycard (Author/Creator)
F. Borget (Author/Creator)
C. Wentrup (Author/Creator)
Publication Details: The Journal of Physical Chemistry A, Vol.112(40), pp.9742-9750
Publisher: ACS Publications
Identifiers: 991005541507507891
Copyright: © 2008 American Chemical Society
Murdoch Affiliation: Murdoch University
Language: English
Resource Type: Journal article

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Collaboration types: Domestic collaboration; International collaboration
Citation topics: 2 Chemistry; 2.1 Synthesis; 2.1.834 Cycloaddition Reactions
Web Of Science research areas: Chemistry, Physical; Physics, Atomic, Molecular & Chemical
ESI research areas: Chemistry