Journal article
Regioselectivity in the reactions of methoxydehydrobenzenes with furans. Part 1. Reactions of 3-methoxydehydrobenzene and 3-(methoxycarbonyl)-dehydrobenzene with 2-substituted furans
Journal of the Chemical Society, Perkin Transactions 1, (6)
1991
Abstract
The isomer ratios for the cycloadducts obtained for the reaction of 3-methoxydehydrobenzene, generated from 2-amino-6-methoxybenzoic acid by aprotic diazotization, or from 2-bromo-3- methoxyphenyl toluene-p-sulphonate by treatment with butyllithium, and for the reaction of 3-(methoxycarbonyl)dehydrobenzene, generated from 2-amino-6-(methoxycarbonyl)benzoic acid by aprotic diazotization, with seven 2-substituted furans are recorded. These results are discussed in terms of an asynchronous, concerted, biradicaloid reaction pathway.
Details
- Title
- Regioselectivity in the reactions of methoxydehydrobenzenes with furans. Part 1. Reactions of 3-methoxydehydrobenzene and 3-(methoxycarbonyl)-dehydrobenzene with 2-substituted furans
- Authors/Creators
- R.G.F. Giles (Author/Creator)M.V. Sargent (Author/Creator)H. Sianipar (Author/Creator)
- Publication Details
- Journal of the Chemical Society, Perkin Transactions 1, (6)
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005540287407891
- Copyright
- © 1991 by the Royal Society of Chemistry.
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
Metrics
21 Record Views