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Scattering theory of close-coupling equations
Journal article   Open access   Peer reviewed

Scattering theory of close-coupling equations

A.T. Stelbovics
Physical Review A - Atomic, Molecular, and Optical Physics, Vol.41(5), pp.2536-2546
1990
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Abstract

The scattering theory implied by the close-coupling equations is studied using a Lippmann-Schwinger formalism. The new results derived can be summarized as follows: An alternative form of the equations that ensures there are no spurious solutions in the scattering region can be constructed, and moreover there is an infinite number of such forms. The Neumann- (perturbation-) series expansion diverges in general for most energies for both the old and new forms. The Born limit nevertheless holds and can be recovered by appropriate rearrangement of the Neumann series. The original integral formulation may give convergent scattering amplitudes despite the lack of uniqueness of the solutions. The conditions under which this happens are examined.

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Citation topics
2 Chemistry
2.15 Physical Chemistry
2.15.664 Dissociative Electron Attachment
Web Of Science research areas
Optics
Physics, Atomic, Molecular & Chemical
ESI research areas
Physics
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