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Solubility equilibria. From data optimization to process simulation
Journal article   Open access   Peer reviewed

Solubility equilibria. From data optimization to process simulation

E. Königsberger
Pure and Applied Chemistry, Vol.74(10), pp.1831-1841
2002
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Abstract

Models that accurately predict solid–solute phase equilibria in aqueous electrolyte solutions are of mounting importance for numerous industrial processes, especially those operating at high temperatures, pressures, and concentrations. The incorporation of such electrolyte models into process simulators is in great demand. This communication will focus on thermodynamically consistent models that can simultaneously predict densities, heat capacities, and apparent molar enthalpies of multicomponent electrolyte mixtures together with activities of their constituents. Data optimization issues to be discussed include the CALPHAD (CALculation of PHAse Diagrams) method applied to electrolyte systems and the generation of robust models that extrapolate well outside the parameterization space. Recent development of software suitable for the simulation of industrial processes involving concentrated electrolyte solutions will be outlined.

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Citation topics
2 Chemistry
2.89 Ionic, Molecular & Complex Liquids
2.89.462 Excess Molar Volumes
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry
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