Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants

G.T. Hefter

doi:10.1515/REVIC.1989.10.1-3.185

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Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants

Journal article

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Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants

G.T. Hefter

Reviews in Inorganic Chemistry, Vol.10(1-3), pp.185-223

1989

DOI: https://doi.org/10.1515/REVIC.1989.10.1-3.185

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Abstract

Thermodynamic data for fluoride salts in non-aqueous and mixed solvents are collected and reviewed. Thermodynamic parameters for the salvation of the fluoride ion have been derived from these data via the tetraphenylarsonium (or phosphonium) tetraphenylborate assumption. Gibbs free energies of transfer of F- from water to pure nonaqueous solvents, obtained mainly from solubility data, often show large discrepancies between independent determinations.

Details

Title: Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants
Authors/Creators: G.T. Hefter (Author/Creator)
Publication Details: Reviews in Inorganic Chemistry, Vol.10(1-3), pp.185-223
Publisher: Walter de Gruyter
Identifiers: 991005544640807891
Murdoch Affiliation: School of Chemical and Mathematical Science
Language: English
Resource Type: Journal article

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