Journal article
Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures
Journal of Solution Chemistry, Vol.13(2), pp.103-119
1984
Abstract
The limiting conductance of various salts of Na+, Ag+, Cu+, Cu2+ and Ph4As+ in acetonitrile-water (AN-H2O) and pyridine-water (Py-H2O) mixtures are reported. Single ion values are calculated for AN-H2O mixtures using the TATB assumption [λo(Ph4As+) = λo(Ph4B-)]. The trends observed for the limiting Walden products (λoη) of the electrolytes and individual ions are discussed in terms of specific ion-solvent interactions and the structural effects of the solvent mixtures.
Details
- Title
- Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures
- Authors/Creators
- P. Singh (Author/Creator) - Murdoch UniversityI.D. MacLeod (Author/Creator) - Murdoch UniversityA.J. Parker (Author/Creator)
- Publication Details
- Journal of Solution Chemistry, Vol.13(2), pp.103-119
- Publisher
- Springer Netherlands
- Identifiers
- 991005544108907891
- Copyright
- © 1984 Plenum Publishing Corporation.
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
Metrics
27 Record Views
InCites Highlights
These are selected metrics from InCites Benchmarking & Analytics tool, related to this output
- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Physical
- ESI research areas
- Chemistry