Journal article
Solvation of ions. XXXI. Partial molal volumes of sodium, silver(I) and copper(I) ions in acetonitrile/water mixtures
Australian Journal of Chemistry, Vol.36(9), pp.1675-1685
1983
Abstract
The partial molal volumes of Na+, Ag+, Cu+, Ph4As+, BPh4-, Cl- and NO3- are reported for transfer from water to various acetonitrile/water (MeCN/H2O) mixtures by using the tatb assumption that ΔVt(Ph4As+) = ΔVt(BPh4-). The results, which show a complex dependence of ionic partial molal volumes on MeCN/H2O solvent composition, are discussed in terms of ion-solvent and solvent-solvent interactions. This study complements earlier work on the energetics of transfer (tatb assumption) of these ions from water to aqueous acetonitrile solutions.
Details
- Title
- Solvation of ions. XXXI. Partial molal volumes of sodium, silver(I) and copper(I) ions in acetonitrile/water mixtures
- Authors/Creators
- P. Singh (Author/Creator)I.D. MacLeod (Author/Creator)A.J. Parker (Author/Creator)
- Publication Details
- Australian Journal of Chemistry, Vol.36(9), pp.1675-1685
- Publisher
- Commonwealth Scientific and Industrial Research Organization Publishing
- Identifiers
- 991005540591807891
- Copyright
- © 1983 CSIRO
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Multidisciplinary
- ESI research areas
- Chemistry