Journal article
Stability constants for the lead(II)-halide systems
Polyhedron, Vol.9(19), pp.2429-2432
1990
Abstract
The stability constants of the complexes of lead(II) with fluoride, chloride, bromide and iodide in aqueous solution have been measured by potentiometric titrations with a lead amalgam at 25°C and an ionic strength of 1.00 M (NaClO4). The overall stability constants show an interesting “mixed” order with log β n for F− > (Cl− < Br− < I−) for n = 1, 2, although the fluoride system shows no tendency to form higher order complexes. The stepwise stability constants for each system show variations which may reflect a change in the coordination number of lead(II) from six to four.
Details
- Title
- Stability constants for the lead(II)-halide systems
- Authors/Creators
- G.T. Hefter (Author/Creator) - Murdoch University
- Publication Details
- Polyhedron, Vol.9(19), pp.2429-2432
- Publisher
- Elsevier
- Identifiers
- 991005540102307891
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.22 Inorganic & Nuclear Chemistry
- 2.22.1278 Stability Constants
- Web Of Science research areas
- Chemistry, Inorganic & Nuclear
- Crystallography
- ESI research areas
- Chemistry