Stability of coordination polymers in water: state of the art and towards a methodology for nonporous materials

A.P. Terzyk; A. Bieniek; P. Bolibok; M. Wiśniewski; P. Ferrer; I. da Silva; P. Kowalczyk

doi:10.1007/s10450-018-9991-9

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Stability of coordination polymers in water: state of the art and towards a methodology for nonporous materials

Journal article

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Stability of coordination polymers in water: state of the art and towards a methodology for nonporous materials

A.P. Terzyk, A. Bieniek, P. Bolibok, M. Wiśniewski, P. Ferrer, I. da Silva and P. Kowalczyk

Adsorption, Vol.25(1), pp.1-11

2019

DOI: https://doi.org/10.1007/s10450-018-9991-9

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Abstract

A mini review on the study concerning water stability of coordination polymers (CPs) is presented. Next, following the procedure proposed recently by Gelfand and Shimizu (Dalton Trans 45:3668-3678, 2016) the stability of three cysteine (Cys)containing CPs is investigated. The stability of studied CPs decreases in the order: Zn(Cys)(2)>Mg(Cys)(2)>Ca(Cys)(2) H2O. For the latternever reported before, the structure is additionally determined and it is proved that water is located in the first coordination sphere. It is shown that for nonporous CPs, in contrast to the porous ones, the immersion in water at 20 degrees C is more drastic for studied solids than the harsh humid conditions (80 degrees C at 90% R.H.). Finally all materials are assigned to the hydrolytic stability groups and it is concluded that the stability of studied CPs correlates well with the standard reduction potentials. This leads to the conclusion that the application of more inert metal as a node causes larger stability of studied CPs.

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Title: Stability of coordination polymers in water: state of the art and towards a methodology for nonporous materials
Authors/Creators: A.P. Terzyk (Author/Creator)
A. Bieniek (Author/Creator)
P. Bolibok (Author/Creator)
M. Wiśniewski (Author/Creator)
P. Ferrer (Author/Creator)
I. da Silva (Author/Creator)
P. Kowalczyk (Author/Creator)
Publication Details: Adsorption, Vol.25(1), pp.1-11
Publisher: Springer US
Identifiers: 991005544958407891
Murdoch Affiliation: School of Engineering and Information Technology
Language: English
Resource Type: Journal article

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Collaboration types: Domestic collaboration; International collaboration
Citation topics: 2 Chemistry; 2.22 Inorganic & Nuclear Chemistry; 2.22.336 Metal-Organic Frameworks
Web Of Science research areas: Chemistry, Physical; Engineering, Chemical
ESI research areas: Chemistry