Journal article
Synthesis, structure and reactivity of a novel series of diastereomeric dirhodium(II) tetracarboxamidates, catalysts for asymmetric diazoacetate transformations
Australian Journal of Chemistry, Vol.51(1), pp.1-8
1998
Abstract
The synthesis and structure of a set of diastereomeric dirhodium(II) tetrakis[methyl (4S)-1-acyl-2oxoimidazolidine-4-carboxylate] compounds are described, including one X-ray crystal structure. With the N-acyl moiety based on the mandelic acid enantiomers, these represent the first examples which incorporate an addititional stereogenic centre in proximity to the axial sites of the dirhodium(II) face. The preliminary catalytic profiles of these diastereomeric complexes are also reported.
Details
- Title
- Synthesis, structure and reactivity of a novel series of diastereomeric dirhodium(II) tetracarboxamidates, catalysts for asymmetric diazoacetate transformations
- Authors/Creators
- G.H.P. Roos (Author/Creator)C.E. Raab (Author/Creator)N.D. Emslie (Author/Creator)M.P. Doyle (Author/Creator)V. Lynch (Author/Creator)
- Publication Details
- Australian Journal of Chemistry, Vol.51(1), pp.1-8
- Publisher
- Commonwealth Scientific and Industrial Research Organization Publishing
- Identifiers
- 991005543960307891
- Copyright
- © CSIRO 1998
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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- Collaboration types
- Domestic collaboration
- International collaboration
- Citation topics
- 2 Chemistry
- 2.1 Synthesis
- 2.1.945 Cyclopropanation Chemistry
- Web Of Science research areas
- Chemistry, Multidisciplinary
- ESI research areas
- Chemistry