Files and links (1)
CC BY V4.0, Open Access
Journal article
The Leaching of Valuable Metals (Li, Co, Ni, Mn, Cu) from Black Mass from Spent Lithium-Ion Batteries
metals, Vol.15(10), 1155
2025
Abstract
Near-complete (>99%) dissolution of lithium and cobalt was achieved by the leaching of black mass from spent (end-of-life) lithium-ion batteries (LiBs) using 4 M H 2 SO 4 or HCl at 60 • C. Raising the temperature to 90 • C did not increase the overall extraction of lithium or cobalt, but it increased the rate of extraction. At 60 • C, 2 M H 2 SO 4 or 2 M HCl performed similarly to the 4 M H 2 SO 4 /HCl solution, although extractions were lower using 1 M H 2 SO 4 or HCl (~95% and 98%, respectively). High extractions were also observed by leaching in low pulp density (15 g/L) at 60 • C with 2 M CH 2 ClCOOH. Leaching was much slower with hydrogen peroxide reductant concentrations below 0.5 mol/L, with cobalt extractions of 90–95% after 3 h. Pulp densities of up to 250 g/L were tested when leaching with 4 M H 2 SO 4 or HCl, with the stoichiometric limit estimated for each test based on the metal content of the black mass. Extractions were consistently high, above 95% for Li/Ni/Mn/Cu with a pulp density of 150 g/L, dropping sharply above this point because of insufficient remaining acid in the solution in the later stages of leaching. The final component of the test work used leaching parameters identified in the previous experiments as producing the largest extractions, and just sulphuric acid. A seven-stage semi-continuous sulphuric acid leach at 60 • C of black mass from LiBs that had undergone an oxidising roast (2h in a tube furnace at 500 • C under flowing air) to remove binder material resulted in high (93%) extraction of cobalt and near total (98–100%) extractions of lithium, nickel, manganese, and copper. Higher cobalt extraction (>98%) was expected, but a refractory spinel-type cobalt oxide, Co 3 O 4 , was generated during the oxidising roast as a result of inefficient aeration, which reduced the extraction efficiency.
Details
- Title
- The Leaching of Valuable Metals (Li, Co, Ni, Mn, Cu) from Black Mass from Spent Lithium-Ion Batteries
- Authors/Creators
- Rorie Gilligan (Author)Glen O'Malley (Author)Aleks Nikoloski - Murdoch University, Centre for Water, Energy and Waste
- Publication Details
- metals, Vol.15(10), 1155
- Publisher
- MDPI
- Identifiers
- 991005821550207891
- Copyright
- © 2025 by the authors.
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
UN Sustainable Development Goals (SDGs)
This output has contributed to the advancement of the following goals:
Metrics
4 File views/ downloads
23 Record Views