The chemistry of Eremophila spp. XXIX: The absolute configuration of (+)-syringaresinol dimethyl ether

I. R Bytheway; E. L Ghisalberti; S Gotsis; P. R Jefferies; B. W Skelton; K. E Sugars; A. H White

doi:10.1071/CH9871913

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The chemistry of Eremophila spp. XXIX: The absolute configuration of (+)-syringaresinol dimethyl ether

Journal article

Peer reviewed

The chemistry of Eremophila spp. XXIX: The absolute configuration of (+)-syringaresinol dimethyl ether

I. R Bytheway, E. L Ghisalberti, S Gotsis, P. R Jefferies, B. W Skelton, K. E Sugars and A. H White

Australian journal of chemistry, Vol.40(11), pp.1913-1917

1987

DOI: https://doi.org/10.1071/CH9871913

Abstract

Analytical, structural and metabolic biochemistry

Aromatic and heterocyclic compounds

Biological and medical sciences

Fundamental and applied biological sciences. Psychology

Heterocyclic compounds, pigments

Other biological molecules

The absolute configuration of the title compound has been established from a single-crystal room temperature X-ray structure determination of its dibromo derivative, C24H28Br2O8. Crystals of the latter are orthorhombic, space group P21212, a l6.696(5), b l5.660(3), c 4.713(1) Å, Z 2; 1452 independent 'observed' reflections yielded R 0.033 following full-matrix least-squares refinement. The molecule lies on a crystallographic 2 axis. The occurrence of lignans in Eremophila species is summarized.

Details

Title: The chemistry of Eremophila spp. XXIX: The absolute configuration of (+)-syringaresinol dimethyl ether
Authors/Creators: I. R Bytheway - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
E. L Ghisalberti - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
S Gotsis - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
P. R Jefferies - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
B. W Skelton - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
K. E Sugars - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
A. H White - Univ. Western Australia, school chemistry, Nedlands W. Aust. 6009, Australia
Publication Details: Australian journal of chemistry, Vol.40(11), pp.1913-1917
Publisher: Commonwealth Scientific and Industrial Research Organization
Number of pages: 5
Identifiers: 991005702686707891
Murdoch Affiliation: Murdoch Business School
Language: English
Resource Type: Journal article

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Citation topics: 3 Agriculture, Environment & Ecology; 3.16 Phytochemicals; 3.16.211 Triterpenoids
Web Of Science research areas: Chemistry, Multidisciplinary
ESI research areas: Chemistry