Journal article
The iron(II)-chromium(VI) reaction: An additional pathway first order in iron(II)
Journal of the Chemical Society A: Inorganic, Physical, Theoretical, pp.2887-2890
1969
Abstract
The iron(II)–chromium(VI) reaction has been studied by platinum-electrode polarography at low (micromolar) iron(II) concentrations. Here an additional term first order in iron(II) appears in the rate equation, which is found to be –d[FeII]/dt=k1H[H+][HCrO4–][FeII]+k2H[HCrO4–][FeII]2/[Fe3+], with k1H= 234 l2 mol–4 s–1 and 10–8k2H= 6·92 l4 mol–4 s–1 at 20 °C and ionic strength 1·00 mol l–1 in sodium perchlorate medium with 0·025–0·065M perchloric acid.
Details
- Title
- The iron(II)-chromium(VI) reaction: An additional pathway first order in iron(II)
- Authors/Creators
- D.R. Rosseinsky (Author/Creator)M.J. Nicol (Author/Creator)
- Publication Details
- Journal of the Chemical Society A: Inorganic, Physical, Theoretical, pp.2887-2890
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005540339907891
- Copyright
- 1969 Royal Society of Chemistry
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
Metrics
139 File views/ downloads
60 Record Views