Logo image
The mechanism of the adsorption of gold cyanide on activated carbon
Journal article   Open access   Peer reviewed

The mechanism of the adsorption of gold cyanide on activated carbon

D.J. McDougall, R.D. Hancock, M.J. Nicol, O.L. Wellington and R.G. Copperthwaite
Journal of the South African Institute of Mining and Metallurgy, Vol.80(9), pp.344-356
1980
pdf
activated carbon.pdfDownloadView
Published (Version of Record) Open Access

Abstract

X-ray photoelectron spectroscopy showed that the adsorption of gold cyanide on carbon in the presence or absence of electrolytes and acids proceeds by the same mechanism. Although the identity of the gold cyanide adsorbate is not known, the mechanism appears to have an initial adsorption stage that involves the adsorption of an ion pair: Mn+[Au(CN).Jn' where Mn+ is a metal ion (for example Na+, K+ and CaH) that has a lower solubility than the Au(CN). anion in the adsorption medium, followed by a reductio:'! step in which either a sub-stoichiometric Au(CN)x surface species or a cluster-type compound of gold is formed.

Details

Metrics

98 File views/ downloads
125 Record Views
Logo image