Journal article
The syntheses of (±)-juglomycin A and (±)-juglomycin B, racemates of two isomeric naturally occurring naphthoquinonoid antibiotics
Journal of the Chemical Society, Perkin Transactions 1, (0), pp.2091-2095
1981
Abstract
Syntheses of the diastereoisomeric 5-hydroxy-2-(4′-hydroxy-γ-butyrolacton-5′-yl)-1,4-naphthoquinones (1) and (2) and their 5-deoxy-analogues (3) and (4) are described. The stereochemistries of the latter, being defined through unambiguous synthesis, permit the assignment of the configurations of (1) and (2)(which were obtained from a single precursor) and also those of the natural products, juglomycins A and B.
Details
- Title
- The syntheses of (±)-juglomycin A and (±)-juglomycin B, racemates of two isomeric naturally occurring naphthoquinonoid antibiotics
- Authors/Creators
- R.G.F. Giles (Author/Creator)P.R.K. Mitchell (Author/Creator)G.H.P. Roos (Author/Creator)J.M.M. Strümpfer (Author/Creator)
- Publication Details
- Journal of the Chemical Society, Perkin Transactions 1, (0), pp.2091-2095
- Publisher
- Royal Society of Chemistry
- Identifiers
- 991005543252207891
- Copyright
- © 1981 Royal Society of Chemistry
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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