Journal article
The use of ion-selective electrodes for the determination of mixed stability constants
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol.39(2), pp.345-355
1972
Abstract
A method is given for evaluating mixed stability constants by the use of ion-selective electrode potentiometry. Data are presented for the lead(II)-fluoride-chloride and fluoride-bromide systems. Mixed complexes PbFCl and PbFBr were detected with stability constants (6±2)×102 and (8±2)×102 l2 mol−2 respectively at ionic strength 1.0 mol l−1 and 25°. Study of the fluoride-iodide system was thwarted by precipitation. Anomalous polarographic behaviour prevented verification of the results by a.c. polarography.
Details
- Title
- The use of ion-selective electrodes for the determination of mixed stability constants
- Authors/Creators
- G. Hefter (Author/Creator)
- Publication Details
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol.39(2), pp.345-355
- Publisher
- Elsevier BV
- Identifiers
- 991005541285807891
- Copyright
- © 1972 Published by Elsevier B.V.
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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