Journal article
Theory of electron-impact ionization of atoms
Physical Review A - Atomic, Molecular, and Optical Physics, Vol.70(6)
2004
Abstract
The existing formulations of electron-impact ionization of a hydrogenic target suffer from a number of formal problems including an ambiguous and phase-divergent definition of the ionization amplitude. An alternative formulation of the theory is given. An integral representation for the ionization amplitude which is free of ambiguity and divergence problems is derived and is shown to have four alternative, but equivalent, forms well suited for practical calculations. The extension to amplitudes of all possible scattering processes taking place in an arbitrary three-body system follows. A well-defined conventional post form of the breakup amplitude valid for arbitrary potentials including the long-range Coulomb interaction is given. Practical approaches are based on partial-wave expansions, so the formulation is also recast in terms of partial waves and partial-wave expansions of the asymptotic wave functions are presented. In particular, expansions of the asymptotic forms of the total scattering wave function, developed from both the initial and the final state, for electron-impact ionization of hydrogen are given. Finally, the utility of the present formulation is demonstrated on some well-known model problems.
Details
- Title
- Theory of electron-impact ionization of atoms
- Authors/Creators
- A.S. Kadyrov (Author/Creator) - Murdoch UniversityA.M. Mukhamedzhanov (Author/Creator) - Texas A&M UniversityA.T. Stelbovics (Author/Creator) - Murdoch UniversityI. Bray (Author/Creator) - Murdoch University
- Publication Details
- Physical Review A - Atomic, Molecular, and Optical Physics, Vol.70(6)
- Publisher
- The American Physical Society
- Identifiers
- 991005545992507891
- Copyright
- © 2004 The American Physical Society
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.15 Physical Chemistry
- 2.15.664 Dissociative Electron Attachment
- Web Of Science research areas
- Optics
- Physics, Atomic, Molecular & Chemical
- ESI research areas
- Physics