Journal article
Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions
Talanta, Vol.144, pp.90-92
2015
Abstract
Pitzer equations are widely employed to correlate and predict the volumetric properties of aqueous electrolyte solutions over broad ranges of pressure and temperature. However, the currently-used pressure and temperature terms are empirical and tend to violate known thermodynamic behaviour. Three functional constraints have been identified that overcome this problem.
Details
- Title
- Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions
- Authors/Creators
- D. Rowland (Author/Creator) - Murdoch University
- Publication Details
- Talanta, Vol.144, pp.90-92
- Publisher
- Elsevier BV
- Identifiers
- 991005542979707891
- Copyright
- © 2015 Elsevier B.V.
- Murdoch Affiliation
- School of Engineering and Information Technology
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Analytical
- ESI research areas
- Chemistry