Journal article
Trianionic organoborate triangles
Inorganic Chemistry, Vol.47(21), pp.9797-9803
2008
Abstract
The rigid, angular ligand 3,3,3′,3′-tetramethyl-1,1′spirobisindane-5,5′,6,6′-tetrol, LH4, in the form of its tetra-anion, L4−, affords crystalline compounds containing the triangular macrocyclic boron derivative [B3L3]3− with the counter cations, triethylammonium, imidazolium, tetraethylammonium, and protonated dabco (dabco = 1,4-diazabicyclo[2,2,2]octane). Within a triangular unit all three chiral L4− ligands have the same hand although the crystal does contain a racemic mixture of macrocycles. In all four compounds, one out of the three counter-cations per macrocycle is bound inside the macrocycle.
Details
- Title
- Trianionic organoborate triangles
- Authors/Creators
- B.F. Abrahams (Author/Creator)B.A. Boughton (Author/Creator)H. Choy (Author/Creator)O. Clarke (Author/Creator)M.J. Grannas (Author/Creator)D.J. Price (Author/Creator)R. Robson (Author/Creator)
- Publication Details
- Inorganic Chemistry, Vol.47(21), pp.9797-9803
- Publisher
- American Chemical Society
- Identifiers
- 991005541514907891
- Copyright
- © 2008 American Chemical Society
- Murdoch Affiliation
- Murdoch University
- Language
- English
- Resource Type
- Journal article
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- 2 Chemistry
- 2.59 Pigments, Sensors & Probes
- 2.59.250 Cyclodextrins
- Web Of Science research areas
- Chemistry, Inorganic & Nuclear
- ESI research areas
- Chemistry