Ultrasonic-Assisted Electrodeposition of Mn-Doped NiCo2O4 for Enhanced Photodegradation of Methyl Red, Hydrogen Production, and Supercapacitor Applications

Kuan-Ching Lee; Timm Joyce Tiong; Guan-Ting Pan; Thomas Chung-Kuang Yang; Kasimayan Uma; Zong-Liang Tseng; Aleksandar N. Nikoloski; Chao-Ming Huang

doi:10.3390/jcs8050164

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Ultrasonic-Assisted Electrodeposition of Mn-Doped NiCo2O4 for Enhanced Photodegradation of Methyl Red, Hydrogen Production, and Supercapacitor Applications

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Ultrasonic-Assisted Electrodeposition of Mn-Doped NiCo2O4 for Enhanced Photodegradation of Methyl Red, Hydrogen Production, and Supercapacitor Applications

Kuan-Ching Lee, Timm Joyce Tiong, Guan-Ting Pan, Thomas Chung-Kuang Yang, Kasimayan Uma, Zong-Liang Tseng, Aleksandar N. Nikoloski and Chao-Ming Huang

Journal of composites science, Vol.8(5), 164

2024

DOI: https://doi.org/10.3390/jcs8050164

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Abstract

electrodeposition

hydrogen production

NiCo2O4

photodegradation

supercapacitor

ultrasonic

This paper presents a novel ultrasonic-assisted electrodeposition process of Mn-doped NiCo2O4 onto a commercial nickel foam in a neutral electroplating bath (pH = 7.0) under an ultrasonic power of 1.2 V and 100 W. Different sample properties were studied based on their crystallinity through X-ray diffraction (XRD), morphology was studied through scanning electron microscopy (SEM), and photodegradation was studied through ultraviolet–visible (UV–Vis) spectrophotometry. Based on the XRD results, the dominant crystallite phase obtained was shown to be a pure single NiCo2O4 phase. The optical properties of the photocatalytic film showed a range of energy band gaps between 1.72 and 1.73 eV from the absorption spectrum. The surface hydroxyl groups on the catalytic surface of the Mn-doped NiCo2O4 thin films showed significant improvements in removing methyl red via photodegradation, achieving 88% degradation in 60 min, which was approximately 1.6 times higher than that of pure NiCo2O4 thin films. The maximum hydrogen rate of the composite films under 100 mW/cm2 illumination was 38 μmol/cm2 with a +3.5 V external potential. The electrochemical performance test also showed a high capacity retention rate (96% after 5000 charge–discharge cycles), high capacity (260 Fg−1), and low intrinsic resistance (0.8 Ω). This work concludes that the Mn-doped NiCo2O4 hybrid with oxygen-poor conditions (oxygen vacancies) is a promising composite electrode candidate for methyl red removal, hydrogen evolution, and high-performance hybrid supercapacitor applications.

Details

Title: Ultrasonic-Assisted Electrodeposition of Mn-Doped NiCo2O4 for Enhanced Photodegradation of Methyl Red, Hydrogen Production, and Supercapacitor Applications
Authors/Creators: Kuan-Ching Lee - University of Nottingham
Timm Joyce Tiong - University of Nottingham Malaysia Campus
Guan-Ting Pan - Murdoch University
Thomas Chung-Kuang Yang - National Taipei University of Technology
Kasimayan Uma - Ming Chi University of Technology
Zong-Liang Tseng - Ming Chi University of Technology
Aleksandar N. Nikoloski - Murdoch University, Centre for Water, Energy and Waste
Chao-Ming Huang - Kun Shan University
Publication Details: Journal of composites science, Vol.8(5), 164
Publisher: MDPI AG
Identifiers: 991005670269507891
Murdoch Affiliation: Murdoch University; Centre for Water, Energy and Waste
Language: English
Resource Type: Journal article

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