Journal article
Use of lithium perchlorate media in the study of protolytic equilibria
Journal of Solution Chemistry, Vol.13(3), pp.179-190
1984
Abstract
A study of the H+/F− system by fluoride ion-selective electrode potentiometry over a range of ionic strengths in LiClO 4 gives protolysis constants which differ markedly from those obtained in other media such as NaClO 4 . This is shown to be consistent with the competitive complexation of the fluoride ion by the lithium ion. An examination of literature data indicates that lithium ion complexation is a general phenomenon and supports the conclusion that LiClO 4 is not preferable to NaClO 4 as a swamping electrolyte for the study of protolytic equilibria as has previously been thought.
Details
- Title
- Use of lithium perchlorate media in the study of protolytic equilibria
- Authors/Creators
- G.T. Hefter (Author/Creator)
- Publication Details
- Journal of Solution Chemistry, Vol.13(3), pp.179-190
- Publisher
- Springer Netherlands
- Identifiers
- 991005543384907891
- Murdoch Affiliation
- School of Mathematical and Physical Sciences
- Language
- English
- Resource Type
- Journal article
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33 Record Views
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Physical
- ESI research areas
- Chemistry