Water adsorption property of hierarchically nanoporous detonation nanodiamonds

E-Z Pina-Salazar; K. Urita; T. Hayashi; R. Futamura; F. Vallejos-Burgos; J. Włoch; P. Kowalczyk; M. Wiśniewski; T. Sakai; I. Moriguchi; A.P. Terzyk; E. Osawa; K. Kaneko

doi:10.1021/acs.langmuir.7b02046

Back

Water adsorption property of hierarchically nanoporous detonation nanodiamonds

Journal article

Peer reviewed

Water adsorption property of hierarchically nanoporous detonation nanodiamonds

E-Z Pina-Salazar, K. Urita, T. Hayashi, R. Futamura, F. Vallejos-Burgos, J. Włoch, P. Kowalczyk, M. Wiśniewski, T. Sakai, I. Moriguchi, …

Langmuir, Vol.33(42), pp.11180-11188

2017

DOI: https://doi.org/10.1021/acs.langmuir.7b02046

Files and links (1)

url

Link to Published Version *Subscription may be requiredView

Abstract

The detonation nanodiamonds form the aggregate having interparticle voids, giving a marked hygroscopic property. As the relationship between pore structure and water adsorption of aggregated nanodiamonds is not well understood yet, adsorption isotherms of N2 at 77 K and of water vapor at 298 K of the well-characterized aggregated nanodiamonds were measured. HR-TEM and X-ray diffraction showed that the nanodiamonds were highly crystalline and their average crystallite size was 4.5 nm. The presence of the graphitic layers on the nanodiamond particle surface was confirmed by the EELS examination. The pore size distribution analysis showed that nanodiamonds had a few ultramicropores with predominant mesopores of 4.5 nm in average size. The water vapor adsorption isotherm of IUPAC Type V indicates the hydrophobicity of the nanodiamond aggregates, with the presence of hydrophilic sites. Then the hygroscopic nature of nanodiamonds should be associated with the surface functionalities of the graphitic shell and the ultramicropores on the mesopore walls.

Details

Title: Water adsorption property of hierarchically nanoporous detonation nanodiamonds
Authors/Creators: E-Z Pina-Salazar (Author/Creator)
K. Urita (Author/Creator) - Nagasaki University
T. Hayashi (Author/Creator)
R. Futamura (Author/Creator)
F. Vallejos-Burgos (Author/Creator)
J. Włoch (Author/Creator) - Nicolaus Copernicus University
P. Kowalczyk (Author/Creator) - Murdoch University
M. Wiśniewski (Author/Creator) - Nicolaus Copernicus University
T. Sakai (Author/Creator)
I. Moriguchi (Author/Creator) - Nagasaki University
A.P. Terzyk (Author/Creator) - Nicolaus Copernicus University
E. Osawa (Author/Creator) - Nano Carbon (Poland)
K. Kaneko (Author/Creator)
Publication Details: Langmuir, Vol.33(42), pp.11180-11188
Publisher: American Chemical Society
Identifiers: 991005543910807891
Murdoch Affiliation: Institute for Immunology and Infectious Diseases
Language: English
Resource Type: Journal article

Metrics

25 Record Views

26 Times Cited - Web of Science

InCites Highlights

These are selected metrics from InCites Benchmarking & Analytics tool, related to this output

Collaboration types: Domestic collaboration; International collaboration
Citation topics: 5 Physics; 5.188 Deposition, Hardening & Coating; 5.188.262 Diamond Films
Web Of Science research areas: Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary
ESI research areas: Chemistry