Journal article
Zdanovskii's rule and isopiestic measurements applied to synthetic Bayer liquors
Journal of Solution Chemistry, Vol.36(11-12), pp.1619-1634
2007
Abstract
Isopiestic measurements of mixed electrolyte solutions involving sodium hydroxide and other components of Bayer liquors were performed at 50∈°C and 100∈°C. Most of the systems studied obey Zdanovskii's rule exactly or very closely. However, those with sodium chloride as one of their components show deviations from Zdanovskii's rule, which are well predicted by our thermodynamic modelling software based on Pitzer's equations.
Details
- Title
- Zdanovskii's rule and isopiestic measurements applied to synthetic Bayer liquors
- Authors/Creators
- E. Königsberger (Author/Creator) - Murdoch UniversityL.C. Königsberger (Author/Creator) - Murdoch UniversityG. Hefter (Author/Creator) - Murdoch UniversityP.M. May (Author/Creator) - Murdoch University
- Publication Details
- Journal of Solution Chemistry, Vol.36(11-12), pp.1619-1634
- Publisher
- Springer Netherlands
- Identifiers
- 991005543736907891
- Copyright
- © 2007 Springer Science+Business Media, LLC.
- Murdoch Affiliation
- School of Chemical and Mathematical Science
- Language
- English
- Resource Type
- Journal article
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- Citation topics
- 2 Chemistry
- 2.89 Ionic, Molecular & Complex Liquids
- 2.89.462 Excess Molar Volumes
- Web Of Science research areas
- Chemistry, Physical
- ESI research areas
- Chemistry